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Lucofin® compounds: engineered for breathable film performance

Breathable masterbatches are typically based on LLDPE or PP and filled with up to 70% calcium carbonate (CaCO₃). In the conversion process, approximately 30% LLDPE is added to the masterbatch before the film is blown. This results in a final film composition containing around 49–50% CaCO₃.

The blown film is then subjected to machine direction orientation (MDO), where it is stretched up to five times its original length. This process creates micro-pores within the film, enabling breathability.

However, the MDO stretching process places significant mechanical stress on the film. As a result, any agglomerates, black spots, or other dispersion-related defects can serve as failure initiation points, potentially leading to film breakage. Therefore, achieving excellent dispersion quality is crucial.

Typically, the film is initially produced with a wall thickness of around 40 microns and then drawn down to approximately 15 microns during the orientation process.

Large industrial machine for the production of film products from Lucofin

Breathable diaper films made easy with Lucofin® compounds

The breathable film – essential for modern hygiene applications – relies heavily on the right polymer-filler combination. Lucofin® Compounds, based on EBA (Ethylene Butyl Acrylate Copolymers), offer outstanding dispersion, process reliability, and mechanical integrity, even under the demanding conditions of MDO stretching with high CaCO₃ loads. This makes them ideal for producing thin, durable, and highly breathable backsheet films for diapers and other personal care products.

IMPROVED LUCOBIT SOLUTION

STATE OF THE ART

Masterbatch with up to 80% СаСО3

Films with 70%, 60%, 50% СаСО3

Grammage 15 and down to 6-10 gsm

OD Stretching 2-3 sufficient

WVTR Blown film without OD Stretch 500 g/m/d

WVTR Cast film without OD Stretch 1800 g/m/d

WTR OD Stretched 2000—12000 g/m/d

Cast and Blown Film grades

Masterbatch with up to 70% СаCO3

Films with 50% max 55% СаСО3

Grammage 15 and down to 10 gsm

OD Stretch up to 5 or 6 Times

NO significant WVTR without OD Stretch

WTR after OD Stretch 4000 g/m/d


Cast and Blown Film grades

Layers of a diaper film

1 Hydrophilic Nonwoven
• Skin contact layer
• Transports liquid quickly to the core
• Soft and gentle for maximum comfort

2 Absorbent Diaper Core
• Superabsorbent polymers (SAP) and fluff pulp
• Stores and distributes liquid
• Keeps moisture away from the skin

3 Waterproof Breathable Film (with Lucofin®)
• Breathable yet liquid-tight
• Produced with LLDPE & 50% CaCO₃
• Printable & stretchable via MDO
• Enables excellent air-permeability

4 PP Nonwoven Backing
• Protective and structural support
• Printable for branding and patterns
• Ensures flexibility and durability

WVTR test method for breathable film using Lucofin® compounds

This WVTR test setup allows for precise, repeatable, and industry-compliant analysis of breathable film properties. It is a critical quality control step in developing and benchmarking Lucofin®-based compounds, ensuring their suitability for highperformance hygiene and medical applications.

To evaluate the breathability of films produced with Lucofin® compounds, the Water Vapor Transmission Rate (WVTR) is measured using a precise and industry-standard testing procedure.

Test Equipment & Standard:
• Instrument: MOCON Permatran-W Model 101K
• Standard: Testing is performed in accordance with ASTM D6701, which is widely accepted for evaluating the water vapor permeability of flexible barrier materials.

Test Conditions:
• Temperature: 37.8 °C (close to skin temperature, relevant for hygiene applications)
• Relative Humidity: 100% – simulating extreme moisture conditions
• Carrier Gas: Nitrogen (N₂), which transports the permeated water vapor from the sample to the detection unit
• These settings mimic real-world conditions in which breathable films are expected to perform, such as in diapers or medical dressings.

Calibration and Accuracy:
• The system is calibrated daily to ensure precise readings.
• The method is highly sensitive to environmental fluctuations, even in climate-controlled rooms, which underlines the need for consistent calibration practices.

Two hands full of colorless plastic granules made of Lucofin

Lucofin® sets new standards in breathable film perfromance

Lucofin® compounds offer a highly efficient and advanced solution for the production of breathable films, outperforming conventional technologies in several key areas. Unlike standard systems, which typically rely on masterbatches with up to 70% calcium carbonate (CaCO₃) and limit film formulations to around 50–55% filler content, Lucofin® allows for masterbatches with up to 80% CaCO₃ and film formulations with 70%, 60%, or 50% filler content. This enables broader formulation flexibility and improved cost-efficiency.

Furthermore, Lucofin® enables the production of films with very low grammage – as low as 6–10 gsm – compared to the industry standard minimum of around 10 gsm. This reduction in material usage contributes to sustainability and lightweight product design.


A major differentiator is the behavior during orientation. While conventional films often require an OD stretching ratio of 5 to 6 times to achieve sufficient breathability, Lucofin®-based films require only 2 to 3 times stretching. This not only reduces energy consumption and mechanical stress on the film but also minimizes the risk of breakage during processing.

Importantly, Lucofin® films show a significant Water Vapor Transmission Rate (WVTR) even without stretching: up to 500 g/ m²/d for blown films and up to 1800 g/m²/d for cast films. After OD stretching, WVTR values of 2000 to 12,000 g/m²/d can be achieved – well above the typical 4000 g/m²/d limit of standard formulations. This high level of breathability contributes directly to product performance and user comfort in hygiene and medical applications.

Finally, Lucofin® compounds are suitable for both cast and blown film production, giving manufacturers maximum flexibility. Combined with better processability, higher whiteness, and softness after stretching, Lucofin® sets a new benchmark for breathable film technology.

Up to 70% CaCo3 in final film and still outstanding

Lucofin®-based breathable film compounds enable a new generation of CaCO₃-filled masterbatches for both breathable and non-breathable applications. Compared to the conventional industry standard of 50% filler content in the final film, Lucofin® formulations allow for significantly higher calcium carbonate loading – up to 60% or even 70% – without compromising performance.

The water vapor permeability (WVTR) of standard OD-stretched films typically reaches around 1,500 g/m²/day. In contrast, films produced using Lucofin® Breathable masterbatches can easily achieve WVTR values of 2,000 g/m²/day, with MOCON-measured performance levels reaching up to 12,000 g/m²/day under optimized conditions.

What is particularly remarkable about these results is that they come despite the higher CaCO₃ content, which traditionally would be expected to reduce mechanical integrity. In fact, Lucofin®-based films maintain – and in some cases improve – mechanical strength and flexibility, offering a unique combination of breathability and durability.

Another important metric is the water column test, which measures a film’s resistance to water penetration under pressure. While standard breathable films typically reach 230 mm, films based on Lucofin® achieve 240 mm, demonstrating strong barrier properties even at higher filler loads.

From a sensory perspective, the haptic quality of Lucofin® films is also enhanced – they feel soft and fine, with a cloth-like texture that improves user comfort in hygiene applications.

Finally, even with a moderate stretch ratio of just 1:1.6, Lucofin® compounds deliver exceptional results in WVTR and film thinness (GSM) – proving that efficient performance does not have to come at the cost of material complexity or excessive stretching.

Thin, strong, breathable – made easy with Lucofin®

This comparison highlights the efficiency and ease of processing of Lucofin® 2071 compounds. Even with a high filler load (60% CaCO₃), Lucofin® films stretch quickly, reach lower grammage faster, and maintain their structure — making them ideal for lightweight, breathable applications.

The bold message “Easy to stretch!” at the bottom reinforces the practical benefit for converters: less effort, faster throughput, and thinner films with consistent quality.

Folder breathable film

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